两种不同颜色C6H4(NH2)2·2HCl的合成及光谱研究          下载免费PDF全文

宋富根  李丽娟  鲁晓明  聂锋  曾忠民  姬连敏  刘志启  冯瑛 《盐湖研究》2009,17(1)

室温下,于CH3OH和H2O的混合溶剂中,钨酸钠存在下邻苯二胺和盐酸反应合成了棕色和红色两种不同颜色的C6H4(NH2)2.2HCl晶体,X-射线单晶衍射分析,晶体属单斜晶系,空间群为C2/c,a=0.7339(2)nm,b=1.4535(5)nm,c=0.8009(3)nm,β=94.041(5)°,V=0.8522(5)nm3,z=4,R1=0.0247,WR2=0.0684。奇特的是棕色晶体与红色晶体均为邻苯二胺盐酸盐,具有相同的晶体结构和IR光谱,但UV光谱呈现出差异。  相似文献   

边界层风廓线雷达在降水时段中的在线分析应用研究     

吴志根 《气象》2012,38(6):758-763

本研究提出了一种在边界层风廓线雷达连续运行的降水探测时段中对降水频谱进行在线分析的新的应用方式。详细介绍了边界层风廓线雷达在线分析原理和方法。同时结合典型降水频谱个例,分析了可获得的多个潜在的气象参数和信息。并指出,该在线分析方式的实施可以使风廓线雷达的应用领域从晴空探测向降水测量拓展;有效缓解当前风廓线雷达应用存在的瓶颈问题;间接证明边界层风廓线雷达组网间距不固定的观点。文章分析说明,随着在线分析方式的推广应用,边界层风廓线雷达将成为单站精细化气象探测和预报/服务的重要工具。  相似文献   

3mm多普勒云雷达测量反演云内空气垂直速度的研究   总被引：7，自引：4，他引：3  

彭亮  陈洪滨  李柏 《大气科学》2012,36(1):1-10

垂直指向的W-波段大气云雷达(WACR)不仅测量云粒子的反射率因子Z, 而且测量多普勒速度谱。本文利用寿县气象站WACR在2008年11月1日一个时段的测量, 进行云内空气垂直速度反演试验。首先讨论个例中反射率、 Doppler平均速度及谱宽的分布特征及原因, 然后利用小粒子示踪法和改进的以小粒子示踪法为基础的粒子下降速度w0—反射率因子 (w0－Z) 关系法反演了云内空气垂直速度, 进而结合Doppler谱数据分析反演结果。结果显示: 小粒子示踪法在湍流较弱时能比较精确地反演空气垂直速度, 而湍流较强时, 湍流造成的误差不可忽略; 改进算法在湍流较强时能够减少湍流对反演结果的影响。  相似文献   

风廓线雷达资料在暴雨天气过程特征分析中的应用     

董保举  付志嘉  李明  杨艳军 《气象科技》2012,40(1):74-78

为了研究风廓线雷达在暴雨天气过程预报中的作用,对2008年6月1日至6月2日云南大理发生的一次暴雨过程进行研究。结果表明,降水前三维风的脉动变化较大,水平风在垂直方向上存在风速切变,最大探测高度明显升高;降水期间可以对降水性质进行判断;降水期间功率谱密度出现双峰谱,能测出垂直气流速度及下降粒子速度,通过这样的分析,便于开展更深层次的降水物理过程研究。  相似文献   

大功率电波加热电离层中热自聚焦不稳定性的理论研究和数值模拟   总被引：3，自引：3，他引：0       下载免费PDF全文

王琛  周晨  赵正予  张援农  杨许铂 《地球物理学报》2015,58(6):1853-1868

本文首先从电子密度及电子温度的输运方程和考虑自作用时的电磁波波动方程出发,利用简正模展开的方法推导出泵波在反射区域激发出热自聚焦不稳定性(thermal self-focusing instabilities,TSFI)所需电场阈值以及其增长率的完整数学表达式,并估算了TSFI激发阈值及所对应的有效辐射功率(ERP)的量级.随后利用三维垂直加热的理论模型,结合国际参考电离层(IRI-2012)和中性大气模型(MSIS-E-00)给出的背景参数,数值模拟了大功率高频泵波加热电离层时泵波反射区域电子密度及电子温度因TSFI而产生的变化及发展的过程,并对比分析了不同背景参数对较热效果的影响.结果表明:当高频泵波的加热阈值达到或超过百毫伏每米的量级时,即可激发TSFI,发展出大尺度电子密度及温度不均匀体,这些不均匀体内的密度耗空约为4%~10%,而电子温度剧烈增长,到达背景温度值的1.6~2.1倍;且在相当的加热条件下,背景电子温度越低、电子密度越小,加热效果越显著;电子密度及电子温度的扰动幅度随着加热时间的推移而逐渐减小,即扰动逐渐趋于饱和,且电子温度要快于电子密度达到饱和状态.本文还对泵波反射高度处的电子密度及电子温度变化率进行采样并求得其功率谱密度,分析结果表明:TSFI发展出的大尺度不均匀体满足幂律谱结构,谱指数随着加热的进行逐渐趋于稳定,白天与夜间的幂律谱指数区别不大,但电子密度与电子温度的幂律谱有所区别.  相似文献   

Intensity measures for probabilistic assessment of non‐structural components acceleration demand          下载免费PDF全文

Marco De Biasio  Stephane Grange  Frederic Dufour  Frederic Allain  Ilie Petre‐Lazar 《地震工程与结构动力学》2015,44(13):2261-2280

A fundamental issue in the framework of seismic probabilistic risk analysis is the choice of ground motion intensity measures (IMs). Based on the floor response spectrum method, the present contribution focuses on the ability of IMs to predict non‐structural components (NSCs) horizontal acceleration demand. A large panel of IMs is examined and a new IM, namely equipment relative average spectral acceleration (E‐ASA_R), is proposed for the purpose of NSCs acceleration demand prediction. The IMs efficiency and sufficiency comparisons are based on (i) the use of a large dataset of recorded earthquake ground motions; (ii) numerical analyses performed on three‐dimensional numerical models, representing actual structural wall and frame buildings; and (iii) systematic statistical analysis of the results. From the comparative study, the herein introduced E‐ASA_R shows high efficiency with respect to the estimation of maximum floor response spectra ordinates. Such efficiency is particularly remarkable in the case of structural wall buildings. Besides, the sufficiency and the simple formulation allowing the use of existing ground motion prediction models make the E‐ASA_R a promising IMs for seismic probabilistic risk assessment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

江苏及邻近地区地震视应力特征研究   总被引：1，自引：0，他引：1  

孙业君  刘红桂  江昊琳  詹小艳  居海华  杨云 《地震研究》2015,38(1)

采用江苏省数字地震台网记录的地震波形资料,利用震源位移谱低频水平与拐角频率计算了2000~2010年江苏及邻近地区561个ML≥1.5中小地震视应力值。结果显示,江苏及邻近地区的地震视应力平均值为0.91 MPa,与中国大陆的平均水平相当。视应力与震级无明显的线性关系,在震级相对较大时表现出一定的高震级对应高视应力的特点。视应力高值地区主要集中在江苏中部至南黄海海域,次高值集中分布在郯庐断裂带中南段的苏鲁交界地区、安徽段固镇至定远附近地区和肥东、巢湖一带,反映了以上地区较高的地震活动水平及地壳应力状态。不同区域ML2震级档视应力的差异性基本反映了区域地质环境、构造活动等特征的差异。  相似文献   

Carbon dioxide segregation in 1:4 and 1:9 CO₂:H₂O ices     

Robert Hodyss  Paul V. Johnson  Grazyna E. Orzechowska  Jay D. Goguen  Isik Kanik 《Icarus》2008,194(2):836-842

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.  相似文献   

Trapping and adsorption of CO₂ in amorphous ice: A FTIR study     

Óscar Gálvez  Belén Maté  Víctor J. Herrero  Rafael Escribano 《Icarus》2008,197(2):599-605

The interaction of carbon dioxide and amorphous water ice at 95 K is studied using transmission infrared spectroscopy. Samples are prepared in two ways: co-deposition of the gases admitted simultaneously or sequential deposition, in which amorphous water ice (ASW) is grown first and CO₂ vapor is added subsequently. In either case, a fraction of the CO₂ molecules is found to interact with water in a way that gives rise to shifts and splittings in the infrared bands with respect to those of a pure CO₂ solid. In co-deposition experiments, a larger amount of carbon dioxide is trapped within the amorphous water than in sequential deposition samples, where a substantial proportion of molecules appears to be trapped in macropores of the ASW. The specific surface area of sequential samples is evaluated and compared to previous literature results. When the sequential samples are heated to 140 K, beyond the onset temperature at which water ice undergoes a phase transition, the CO₂ molecules at the pores relocate inside the bulk in a structure similar to that found in co-deposited samples, as deduced by changes in the shape of the CO₂ infrared bands.  相似文献   

The coating hypothesis for ammonia ice particles in Jupiter: Laboratory experiments and optical modeling     

Konstantinos S. Kalogerakis  Jochen Marschall  Patricia A. Engel  Rhiannon T. Meharchand  Michael H. Wong 《Icarus》2008,196(1):202-215

We report laboratory experiments and modeling calculations investigating the effect of a hydrocarbon coating on ammonia ice spectral signatures. Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in areas of strong vertical transport, indicating a short lifetime for the signature of ammonia absorption on condensed ammonia particles [Baines, K.H., Carlson, R.W., Kamp, L.W., 2002. Icarus 159, 74-94]. Current literature has suggested coating of ammonia ice particles by a hydrocarbon haze as a possible explanation for this paradox. The work presented here supports the inference of a coating effect that can alter or suppress ammonia absorption features. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by reflection-absorption infrared spectroscopy. We have observed the effects on the ammonia ice absorption features near 3 and 9 μm with coverage by thin layers of hydrocarbons. Modeling calculations of these multilayer thin films assist in the interpretation of the experimental results and reveal the important role of optical interference in altering the aforementioned ammonia spectral features. Mie and T-matrix scattering calculations demonstrate analogous effects for ammonia ice particles and investigate the relative effects of ammonia ice particle size, shape, and coating layer thickness on the ice particle spectral signatures.  相似文献